红土镍矿成球行为及氧化固结机理
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张庆禹(2001—),男,硕士研究生,从事低碳炼铁、资源综合利用方面的研究。

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TF046. 6

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国家自然科学基金资助项目(52404341);中国宝武低碳冶金创新基金资助项目(BWLCF202313);中央高校基本科研业务专项资金(N25ZJL001);中央高校基本科研业务专项资金(N26LPY026)


Pelletization behavior and oxidation consolidation mechanism of laterite nickel ore
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    摘要:

    造块工艺作为红土镍矿入电炉前重要的预处理流程,是降低电炉能耗、提高有价组元回收和降低环境负荷的有效手段。本文主要采用造球试验、预热—焙烧试验、热分析、热力学相图计算以及XRD、SEM-EDS 等表征手段,系统研究了典型红土镍矿的成球行为和氧化固结机理,以获得强度适宜的红土镍矿氧化球团。结果表明,红土镍矿氧化球团主要物相为Fe2 O3 、CaMgSi2 O6 、[(Mg,Fe)O·Fe2 O3 ]和Mg2 SiO4 ,其中Fe2 O3 、[(Mg,Fe)O·Fe2 O3 ]、(Mg2 SiO4 )起骨架作用,CaMgSi2 O6 作为黏结相,进而提高球团的固结特性。此外,提高焙烧温度和优化碱度对球团黏结相生成有显著的促进作用。在碱度为0. 15、预热温度为950 ℃(持续15 min)及焙烧温度为1 300 ℃(持续15 min)的条件下,可得到抗压强度为1 983 N/ P 的红土镍矿氧化球团,满足后续工艺要求。

    Abstract:

    The agglomeration process,as an important pretreatment step before laterite nickel ore is fed into the electric furnace,represents an effective means to reduce energy consumption in the electric furnace,enhance the recovery of valuable components, and reduce environmental burden. Pelletizing tests, preheating-roasting tests, thermal analysis, thermodynamic phase map calculations,as well as XRD,SEM-EDS characterization methods are mainly adopted, the pelletization behavior and oxidation-consolidation mechanisms of typical laterite nickel ores are systematically studied, aiming to obtain oxidation pellets of laterite nickel ore with appropriate strength. The results show that the main phases of oxidized pellets in the laterite nickel ore are Fe2 O3 ,CaMgSi2 O6 ,[(Mg,Fe) O·Fe2 O3 ],and Mg2 SiO4 ,among which Fe2 O3 ,[(Mg,Fe) O·Fe2 O3 ],(Mg2 SiO4 ) act as the framework,while CaMgSi2 O6 acts as the binder phase,thereby enhancing the consolidation properties of the pellets. In addition,increasing the roasting temperature and optimizing the basicity have a significant positive effect on the formation of the agglutinating phase in pellets. Under conditions of alkalinity of 0. 15,preheating temperature of 950 ℃ (for 15 min),and calcination temperature of 1 300 ℃ (for 15 min), laterite nickel ore oxide pellets with compressive strength of 1 983 N/ p can be obtained,meeting the requirements of subsequent processes.

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张庆禹,田宏宇,储满生,唐 珏,李 峰.红土镍矿成球行为及氧化固结机理[J].烧结球团,2026,51(3):58-66

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  • 最后修改日期:2025-12-01
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  • 在线发布日期: 2026-07-23
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