钢渣低液固比湿法矿化固定CO2的工艺优化与固碳性能
CSTR:
作者:
作者单位:

作者简介:

金秋彤(2001—),女,硕士研究生,从事工业烟气碳减排方面的研究。

通讯作者:

中图分类号:

X757

基金项目:

国家自然科学基金地区科学基金资助项目(22068029);内蒙古自然科学基金资助项目(2022QN05015)


Process optimization and carbon sequestration performance of CO2 fixation by low liquidsolid ratio wet process mineralization of steel slag
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    在“双碳”战略目标背景下,矿化固定技术作为一种重要的CO2 减排途径日益受到重视。作为一种富含碱性物质的钙基工业固废,钢渣已成为固定CO2 的理想廉价原料。本文采用低液固比湿法矿化方法研究不同液固比、温度及压力对固碳率的影响及最佳工艺条件,并采用XRD、XRF 等手段分析钢渣和固碳产物的矿相组成和微观结构。结果表明:低液固比湿法矿化方法通过降低水耗与能耗,强化反应的传质效率,协同实现经济高效的钢渣固废资源化与CO2 封存。受水膜厚度的影响,液固比存在最优值。100 ℃、0. 85 MPa、450 r/ min 条件下,当液固比由0. 2 mL/ g 提升至0. 4 mL/ g 时,固碳率由11. 8% 提升到21. 2%,继续提高液固比至1 mL/ g 后固碳率反而下降为9. 3%,说明适当的水膜厚度有助于传质过程;固碳率随着温度、压力的升高呈现增加的趋势,在液固比为0. 6 mL/ g的条件下,当温度由25 ℃提升至100 ℃时,固碳率由4. 8%提升至20. 9%,压力由0. 85 MPa 提升至2. 85 MPa,固碳率由20. 9%提升至27. 6%,过高的温度及压力会导致固碳率的增幅下降及能耗增加。综合来看,在反应温度为100 ℃、液固比为0. 6 mL/ g、压力为2. 85 MPa、时间为1 h 及搅拌速率为450 r/ min 的最优工艺组合条件下,钢渣的固碳率为27. 6%,即最大固碳量为276 g/ kg。

    Abstract:

    In the context of the “dual carbon” strategic goal,mineralization fixation technology has received increasing attention as an important CO2 emission reduction pathway. As a calcium-based industrial solid waste rich in alkaline substances,steel slag has become an ideal and inexpensive raw material for CO2 fixation. In this paper,the effects of different liquid-solid ratios,temperature and pressure on carbon sequestration rate and the optimal process conditions are studied by low liquid-solid ratio wet process mineralization method,and the phase composition and microstructure of steel slag and carbon sequestration products are analyzed by XRD and XRF. The results show that the low-liquid-solid radio wet process mineralization method synergistically realizes cost-effective steel slag solid waste recycling and CO2 storage by reducing water consumption and energy consumption and enhancing the mass transfer efficiency of the reaction. Affected by the thickness of the water film,there is an optimal value of liquid-solid ratio. Under the conditions of 100 ℃,0. 85 MPa, and 450 r/ min,when the liquid-solid ratio is increased from 0. 2 mL/ g to 0. 4 mL/ g,the carbon sequestration rate is increased from 11. 8% to 21. 2% . However,when the liquid-to-solid ratio is further increased to 1 mL/ g,the carbon sequestration rate is decreased to 9. 3%,indicating that an appropriate thickness of the water film is beneficial for the mass transfer process. The carbon sequestration rate shows an increasing trend with rising temperature and pressure. For a liquidsolid ratio of 0. 6 mL/ g,when the temperature is increased from 25 ℃ to 100 ℃,the carbon sequestration rate is increased from 4. 8% to 20. 9%;when the pressure is increased from 0. 85 MPa to 2. 85 MPa,the carbon sequestration rate is increased from 20. 9% to 27. 6% . However,excessively high temperatures and pressures can lead to a decrease in the increase in carbon sequestration rate as well as an increase in energy consumption. In summary,under the optimal process combination of reaction temperature of 100 ℃,reaction liquid-solid ratio of 0. 6 mL/ g,reaction pressure of 2. 85 MPa, reaction time of 1 h and stirring rate of 450 r/ min,the carbon sequestration rate of steel slag is 27. 6%,that is,the maximum carbon sequestration is 276 g/ kg.

    参考文献
    相似文献
    引证文献
引用本文

金秋彤,房洪彬,张小霞,龚志军.钢渣低液固比湿法矿化固定CO2的工艺优化与固碳性能[J].烧结球团,2026,(2):108-117

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2025-11-20
  • 录用日期:
  • 在线发布日期: 2026-07-21
  • 出版日期:
文章二维码