气基竖炉富氢气氛下赤铁矿还原的热力学研究
CSTR:
作者:
作者单位:

作者简介:

张晓萍(1982—),女,高级工程师,从事炼铁新技术与理论方面的研究。

通讯作者:

中图分类号:

TF554

基金项目:

安徽省重大产业创新计划资助项目(AHZDCYCXLSDT2023-01)


Thermodynamic study on reduction of hematite in a hydrogen rich atmosphere in a gasbased shaft furnace
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    为评估富H2 含CO 气基竖炉工艺中赤铁矿的还原行为, 研究基于最小吉布斯自由能原理, 利用HSCChemistry 9. 5. 1 软件构建热力学模型,分析在固定反应气的物质的量为3 kmol 条件下,气体成分与温度对铁氧化物还原路径及平衡物相组成的影响。结果表明:单一还原剂条件下,H2 在1 000 ℃时可完全还原赤铁矿的临界量为0. 405 kmol;CO 在700 ~800 ℃时还原能力达到最强,临界量为0. 415 kmol,但超过800 ℃后,CO 受高温逆向反应制约还原能力减弱。增加还原剂配比可促进磁铁矿与浮氏体向金属铁转化。H2 中引入约40% CO 可拓宽还原温度窗口,弥补纯H2 低温区( <700 ℃)还原能力不足与纯CO 高温区( >800 ℃)还原势衰减的缺陷,在800 ℃左右有效提升金属铁产率。典型气基竖炉工艺还原能力排序为HyMEX≈HYL - III > Midrex,其中Midrex 工艺完全还原赤铁矿的最高处理量为0. 352 5 kmol,而HYL - III 与HyMEX 工艺分别可达0. 395 kmol 和0. 400 kmol,后两者因富H2 气氛更适应高温还原。本文研究成果可为优化气基竖炉的还原工艺参数提供理论依据。

    Abstract:

    In order to evaluate the reduction behavior of hematite in the H2 -rich CO-containing gas-based shaft furnace process,a thermodynamic model is constructed by using HSC Chemistry 9. 5. 1 software based on the minimum Gibbs free energy principle, and the effects of gas composition and temperature on the reduction path of iron oxides and the composition of the equilibrium phase are analyzed under the condition of fixed reaction gas molar (3 kmol). The results show that the critical amount of H2 that could completely reduce hematite at 1 000 ℃ is 0. 405 kmol. The reduction ability of CO reaches to the strongest at 700 ~ 800 ℃,and the critical amount is 0. 415 kmol,but after exceeding 800 ℃,the reduction ability of CO is restricted by the reverse reaction of high temperature and weakened. Increasing the proportion of reducing agents can promote the conversion of magnetite and floatonite to metallic iron. The introduction of about 40% CO into H2 can broaden the reduction temperature window,make up for the lack of reduction capacity in the low temperature region of pure H2 ( <700 ℃) and the attenuation of the reduction potential in the high temperature region of pure CO ( >800 ℃),and effectively improve the yield of iron metal at about 800 ℃. The reduction capacity of typical gas-based shaft furnace processes is ranked by HyMEX≈HYL-III > Midrex,among which the maximum treatment capacity of fully reduced hematite by the Midrex process is 0. 352 5 kmol,while the HYL-III and HyMEX processes could reach 0. 395 kmol and 0. 400 kmol,respectively. The latter two are more suitable for high temperature reduction due to H2 -rich atmosphere. The results can provide a theoretical basis for optimizing the reduction process parameters of gas-based shaft furnaces

    参考文献
    相似文献
    引证文献
引用本文

张晓萍,温宝良,宋灿阳,杨佳龙.气基竖炉富氢气氛下赤铁矿还原的热力学研究[J].烧结球团,2026,(2):93-101

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2025-11-07
  • 录用日期:
  • 在线发布日期: 2026-07-21
  • 出版日期:
文章二维码