钒钛球团热强度及其影响因素
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Hot strength of vanadium-titanium pellets and its influencing factors
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    摘要:

    为揭示在低碳炼铁高配比球团冶炼背景下钒钛球团的热力学行为,本文系统考察了温度、气氛和还原时间 对钒钛球团热抗压强度的影响。采用热强度测定仪,并结合X射线行射(XRD)和光学显微镜等手段,分析了球团 在不同条件下的强度演变、物相转变及显微组织变化。结果表明:在N2情性气氛下,球团抗压强度随温度升高呈 先增加后降低的趋势,在800 ℃时达到峰值(2 992.2 N/P),此阶段主要由固相烧结引起的致密化效应所致;在 900 ℃下引入含CO/CO2的还原气氛后,球团强度迅速下降至1 000 N/P左右,主要原因是Fe2O3向Fe3O4。的相变 伴随晶格与体积变化,破坏了原有烧结骨架;在还原气氛中,随着还原时间的延长,强度在第1.0 h内急剧下降,随 后在较低水平波动,这是还原诱导的结构损伤与高温再烧结修复相互竞争的结果。本研究揭示了钒钛球团在模 拟高炉上中部环境下的热强度演化机理,可为高配比球团在高炉冶炼中的稳定应用与操作优化提供理论依据。

    Abstract:

    To reveal the thermodynamic mechanical behavior of vanadium-titanium pellets under the condition of low- carbon ironmaking with high high-proportion pellets,in the study of this paper,the effects of temperature,atmosphere,and reduction time on the thermal compressive strength of vanadium-titanium pellets were systematically investigated. A thermal strength tester combined with X-ray diffraction(XRD) and optical microscopy,the strength evolution was used to analyze the phase transformations,and microstructural changes of the pellet under different conditions. The results showed that at the inert N2 atmosphere,the compressive strength of the pelets initially increased and then decreased with the temperature rising,and it reached its peak value(2 992.2 N/P) at 80 ℃,at this period,it was primarily due to densification effects fromsolid-phasesintering.When a reducing atmospherecontaining CO/CO2 wasintroducedat 90oC,the pelets strength rapidly declined to approximately 1 OOo N/P,mainly due to the phase transformation of Fe2 O3 to Fe3O4 accompanied by lattice and volume changes,which disrupted the original sintered structure. In the reducing atmosphere,with the reduction time extending the strength sharply decreased within the first l. O h of reduction and then fluctuated at a lower level, which is attributed to the competition between reduction-induced structural damage and high-temperature re-sintering repair. This studyrevealedthestrengthevolutionmechanismofvanadium-titaniumpelletsunderthesimulatedconditionsof theupper blast furnace,which can provide a theoretical basis for the stable application and operational optimization of high-proportion pellets in blast furnace smelting.

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张立利,朱伟,马凯辉,刘凌岭,陈茅.钒钛球团热强度及其影响因素[J].烧结球团,2026,(1):188-195

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  • 在线发布日期: 2026-03-25
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