烧结用生物质炭燃料制备及其性能研究
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作者单位:

辽宁科技大学 a.材料与冶金学院 ; b.辽宁省绿色低碳与智能冶金重点实验室,辽宁 鞍山 114051

作者简介:

辛闯(2000—),男,硕士研究生,从事生物质燃料和生物质烧结研究。

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中图分类号:

TK6;TF54

基金项目:

国家自然科学基金资助项目( 52374339&52474359) ; 中国宝武低碳冶金创新基金资助项目( BWLCF202308)


Research on preparation and performance of biochar fuel for sintering
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University of Science and Technology Liaoning a.School of Materials and Metallurgy ;b.Key Laboratory of GreenLow-Carbon and Intelligent Metallurgy,Anshan 114051 ,Liaoning,China

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    摘要:

    为了探寻铁矿粉烧结用清洁型燃料,降低焦粉使用,本文利用两段炭化( 即第一段炭化温度分别升至 300、 350、400 ℃保温 30 min,第二段炭化温度升至 600 ℃保温 30 min) 和一段炭化( 直接升温至 600 ℃,中间不保温) 共 4 种工艺对木屑进行炭化,制备生物质炭。同时,分析了不同工艺下生物质炭的基础性能并且采用热重法对生物质炭-焦粉混合燃烧特性进行了试验研究。结果表明: 与生物质相比,生物质炭具有较低的挥发分和较高的固定碳和热值,且结构更加致密,但是比焦粉的结构更疏松且多孔洞。一段炭化的生物质炭产率最高,产生热解气中的 CO、CH4、H2含量最高,CO2含量最低。4 种炭化工艺中,采用一段炭化工艺生物质炭的着火点、燃尽温度、峰值温度最低,燃烧特性指数和平均失重速率最大,活化能最低,燃烧性最好。与焦粉相比,生物质炭-焦粉混合燃烧时具有更低的着火点、燃尽温度,燃烧性能更好。此外,生物质炭-焦粉混合燃烧时表现出两个主要阶段: 低温区时以生物质炭燃烧为主的“燃烧阶段 I”,高温区以焦粉燃烧为主的“燃烧阶段 II”。

    Abstract:

    In order to explore the clean fuel for iron ore powder sintering and reduce the use of coke powder,four processes are used to carbonize wood chips and prepare biochar by two carbonization processes ( i. e.,the first carbonization temperature rises to 300,350 and 400 ℃ for 30 min,respectively,and the second carbonization temperature rises to 600 ℃ for 30 min) and one carbonization ( directly heating to 600 ℃ without insulation in the middle) . At the same time,the basic properties of biochar under different processes are analyzed,and the mixed combustion characteristics of biochar and coke powder are experimentally studied by thermogravimetric method. The results show that,compared with biomass, biochar has lower volatile content and higher fixed carbon and calorific value,and the structure is denser,but the structure is looser and more porous than that of coke powder. The biochar yield of the carbonized stage is the highest,and the content of CO,CH4 and H2 in the pyrolysis gas is the highest,and the CO2 content is the lowest. Among the four carbonization processes,the ignition point,burnout temperature and peak temperature of biomass charcoal using a carbonization process are the lowest,the combustion characteristic index and average weight loss rate are the largest,the activation energy is the lowest,and the flammability is the best. Compared with coke powder,biochar-coke powder has a lower ignition point,burnout temperature and better combustion performance when combusted by biochar-coke powder. In addition,there are two main stages in the mixed combustion of biochar and coke powder: “combustion stage I”dominated by biochar combustion in the low temperature area,and“combustion stage II”with coke powder combustion in the high temperature area.

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引用本文

辛闯,唐超,何志军,刘吉辉.烧结用生物质炭燃料制备及其性能研究[J].烧结球团,2025,50(5):77-84

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  • 收稿日期:2025-04-28
  • 最后修改日期:2025-05-19
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  • 在线发布日期: 2025-11-11
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