气基竖炉内直接还原铁黏结机理研究
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作者单位:

1.浙江工贸职业技术学院 材料工程系,浙江 温州 325000 ;2.兰州理工大学 材料科学与工程学院,甘肃 兰州 730050

作者简介:

唐恩(1979—),男,博士,教授,从事非高炉炼铁方面的研究工作。

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中图分类号:

TF55

基金项目:

温州市基础公益项目(G2023068);浙江工贸引进人才项目(YJRC202305)


Research on bonding mechanism of DRI in gas⁃based shaft furnace
Author:
Affiliation:

1.Materials Engineering Department,Zhejiang Industry & Trade Vocational College,Wenzhou 325000 ,Zhejiang,China ;2.School of Materials Science and Engineering,Lanzhou University of Technology,Lanzhou 730050 ,Gansu,China

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    摘要:

    为探究气基竖炉内直接还原铁(DRI)的黏结机理,分析黏结现象与生产工艺的内在联系,本文通过冷固结球团高温还原试验模拟竖炉直接还原过程,采用扫描电镜(SEM)和能谱分析(EDS)对还原后球团的形貌、成分及黏结结构进行观察与表征。 结果表明,球团间黏结物的 TFe 质量分数高达 93. 56% ,碎屑黏结物因脉石富集导致 TFe 质量分数较低为 53. 88% ;球团之间的黏结主要由还原后铁元素的聚集与长大导致,其过程可分为低于 800 ℃ 的低温固相烧结和 800 ~ 900 ℃的高温还原融合两个阶段。 黏结形态受颗粒接触、扩散及高温融合共同影响,其中, 高温阶段铁原子的扩散与再结晶是黏结强化的关键。 DRI 的黏结现象不可避免,但可通过控制原料强度、还原温度、金属化率等条件减轻黏结程度。 本文研究成果可为优化气基竖炉生产工艺、提高 DRI 产品质量提供理论依据。

    Abstract:

    In order to explore the bonding mechanism of DRI in gas-based shaft furnaces and analyze the internal relationship between the bonding phenomenon and the production process,the direct reduction process of the shaft furnace is simulated by cold-consolidated pellets by high-temperature reduction test,and the morphology,composition and bond structure of the reduced pellets are observed and characterized by SEM and EDS. The results show that the TFe mass fraction of the inter-pellet binder is as high as 93. 56% ,and the TFe mass fraction of the clastic binder is low at 53. 88% due to gangue enrichment. The bonding between pellets is mainly caused by the aggregation and growth of iron after reduction,and the process can be divided into two stages:low-temperature solid-phase sintering below 800 ℃ and high- temperature reduction fusion at 800 ~ 900 ℃. The bonding morphology is affected by particle contact,diffusion and high- temperature fusion,among which the diffusion and recrystallization of iron atoms at high temperature stage are the key to bond strengthening. DRI bonding is unavoidable,but the degree of bonding can be reduced by controlling the strength of the raw material,reduction temperature,metallization rate,etc. The results can provide a theoretical basis for optimizing the production process of gas-based shaft furnaces and improving the quality of DRI products.

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唐恩,陈洋杨,吕维嘉,张瑞,王坤,胡一迪.气基竖炉内直接还原铁黏结机理研究[J].烧结球团,2025,50(4):106-113

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  • 收稿日期:2024-06-25
  • 最后修改日期:2024-08-04
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  • 在线发布日期: 2025-11-06
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