生物质含碳球团还原过程的影响因素及其动力学行为
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作者单位:

安徽工业大学 冶金工程学院,安徽 马鞍山 243032

作者简介:

方书霖(2004—),男,从事绿色低碳炼铁方面的研究。

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中图分类号:

TF046.6;X712

基金项目:

国家自然科学基金资助项目(52074080);安徽省大学生创新创业训练计划资助项目(S202310360169)


Influencing factors and dynamics behavior of biomass carbon⁃containing pellets reduction process
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School of Metallurgical Engineering,Anhui University of Technology,Ma’anshan 243032 ,Anhui,China

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    摘要:

    “双碳”背景下非高炉炼铁工艺技术开发已成为低碳冶金的重要内容。 作为一种富含 C、H 元素的可再生能源,生物质被碳化处理后可作为转底炉含碳球团的还原介质替代原料,该项研究对进一步降低碳排放,推动含碳球团技术发展具有重要的现实意义。 本文选取核桃壳、瓜子壳和花生壳三种生物质炭为还原剂制备含碳球团,研究生物质炭种类、温度和时间对含碳球团还原过程和动力学的影响,确定还原过程的动力学限制性环节。 结果表明,温度对生物质含碳球团还原的影响显著,升高温度能有效促进铁氧化物还原。 花生壳热解炭质地疏松、比表面积大,该结构特性展现出良好的还原性能。 以花生壳生物质炭制备的球团在1 100 ℃下还原20 min 后反应分数达到 86. 61% 。 扩散过程是花生壳基含碳球团还原过程的限制性环节,其表观活化能为 63. 886 kJ/ mol。 本文研究成果将为生物质含碳球团的实际应用提供理论基础和技术支撑。

    Abstract:

    The development of non-blast furnace ironmaking technology under the background of carbon peaking and carbon neutrality has become an important part of low-carbon metallurgy. Biomass is a renewable energy rich in C and H elements,and it is of great practical significance to further reduce carbon emissions and promote the development of carbon- containing pellets technology after carbonization treatment as a substitute raw material for carbon-containing pellets in rotary hearth furnaces. In this paper,three kinds of biochar including walnut shell,melon seed shell and peanut shell,are selected as reducing agents to prepare carbon-containing pellets,and the effects of carbon type,temperature and time on the reduction process and dynamics of carbon-containing pellets are studied,and the dynamics constraints of the reduction process are determined. The results show that temperature has a significant impact on the reduction of carbonaceous pellets in biomass,and increasing the temperature can effectively promote iron oxide reduction. The peanut shell pyrolytic carbon has a loose texture and a large specific surface area. This structural characteristic shows good reduction performance. The pellets prepared from the biomass are reduced at 1 100 °C for 20 min and the reaction fraction can reach to 86. 61%. The diffusion process is the limiting link in the reduction process of carbon-containing pellets in peanut shell,and its apparent activation energy is 63. 886 kJ/ mol. This study will provide a theoretical basis and technical support for the practical application of biomass carbon-containing pellets.

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引用本文

方书霖,王浩,孙武,宋民伟,张邹明,王宏涛.生物质含碳球团还原过程的影响因素及其动力学行为[J].烧结球团,2025,50(4):64-72

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  • 收稿日期:2024-12-27
  • 最后修改日期:2025-02-24
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  • 在线发布日期: 2025-11-06
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