复合黏结剂球团的制备与固结机制
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作者单位:

1.中南大学 资源加工与生物工程学院,湖南 长沙 410083 ;2.湘潭瑞通球团有限公司 技术中心,湖南 湘潭 411101 ;3.湖南华菱湘潭钢铁集团有限公司 技术中心,湖南 湘潭 411101

作者简介:

姜文政(2000—),男,硕士研究生,从事钢铁冶金、资源综合利用等方面的研究。

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中图分类号:

TF046.6

基金项目:

国家重点研发计划资助项目(2020YFC1909805);中南大学研究生自主探索创新项目(2025ZZTS0093);中国宝武低碳冶金创新基金资助项目(BWLCF202103)


Preparation and consolidation mechanism of composite binder pellets
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1.School of Minerals Processing and Bioengineering,Central South University,Changsha 410083 ,Hunan,China ;2.Technology center,Xiangtan Ruitong Pellet Co.,Ltd.,Xiangtan 411101 ,Hunan,China ;3.Technology center,Hunan Valin Xiangtan Iron and Steel Group Co.,Ltd.,Xiangtan 411101 ,Hunan,China

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    摘要:

    膨润土作为球团矿生产的主要黏结剂,主要成分为 SiO2 、Al 2O3 等脉石矿物,其大量配入将降低球团的铁品位,增加高炉炼铁的成本和燃料消耗。 因此,亟需开发新的黏结剂部分或完全替代膨润土,降低球团生产中膨润土的用量。 本文采用 M 黏结剂制备生球,采用优化后的预热焙烧制度制备一种复合黏结剂球团,同时采用 XRD、 光学显微镜等检测手段分析复合黏结剂球团的矿物组成和微观机构,阐明复合黏结剂球团的固结机制。 研究结果表明:采用 0. 1% M 黏结剂 + 0. 5% 膨润土的复合黏结剂,在造球时间为 12 min、造球水分为 8. 0% 、1 010 ℃下预热 10 min 和 1 220 ℃下焙烧 10 min 的优化条件下,经性能检测,所制备生球的落下强度为 4. 1 次/ (0. 5 m),爆裂温度为 460 ℃ ,抗压强度为 17. 43 N/ P;经过预热和焙烧后,球团抗压强度分别显著提升至 527 N/ P 与 3 077 N/ P。 与 1% 膨润土球团相比,采用复合黏结剂造球后,膨润土用量减少 50% ,球团质量明显提高,赤铁矿含量更高,脉石含量降低。 复合黏结剂球团在预热焙烧过程中主要发生磁铁矿氧化-赤铁矿高温再结晶反应,主要矿物为赤铁矿以及少量的硅酸盐和石英;相较于膨润土球团,赤铁矿再结晶作用更强,成片的赤铁矿区域更大,单独的赤铁矿晶粒较少。 复合黏结剂球团的固结方式主要以 Fe2O3 的再结晶固结为主,同时辅以硅酸盐液相黏结,使球团形成均匀致密的微观结构。

    Abstract:

    As the main binder in pellet ore production,bentonite is mainly composed of gangue minerals such as SiO2 and Al 2O3 ,and its large amount of combination will reduce the iron grade of pellets and increase the cost and fuel consumption of blast furnace ironmaking. Therefore,there is an urgent need to develop new binders to partially or completely replace bentonite and reduce the amount of bentonite in pellet production. In this paper,a composite binder pellet is prepared by using M binder,and a composite binder pellet is prepared by optimized preheating and roasting system,and the mineral composition and microstructure of the composite binder pellets are analyzed by XRD,optical microscopy and other detection methods,and the consolidation mechanism of the composite binder pellets is elucidated. The results show that the falling strength of the prepared fresh pellets is 4. 1 times/ (0. 5 m),the burst temperature is 460 ℃ ,and the compressive strength is 17. 43 N/ P under the optimal conditions of pelletizing time of 12 min, pelletizing moisture of 8. 0% , preheating at 1 010 ℃ for 10 min and roasting at 1 220 ℃ for 10 min;After preheating and roasting, the compressive strength is significantly increased to 527 N/ P and 3 077 N/ P, respectively. Compared with 1% bentonite pellets, the amount of bentonite is reduced by 50% ,the pellet mass is significantly improved,the hematite content is higher,and the gangue content is reduced. The preheating and roasting process of the composite binder pellets mainly undergoes magnetite oxidation-hematite high-temperature recrystallization reaction,and the main minerals are hematite and a small amount of silicate and quartz. Compared with bentonite pellets,hematite recrystallization is stronger,the hematite area is larger,and there are fewer individual hematite grains. The consolidation method of composite binder pellets is mainly based on the recrystallization consolidation of Fe2O3 ,supplemented by silicate liquid phase bonding,to form a uniform and dense pellet microstructure.

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姜文政,谢路奔,项思敏,文小平,高梓朔,吴云,钟强,李光辉.复合黏结剂球团的制备与固结机制[J].烧结球团,2025,50(4):56-63

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  • 收稿日期:2024-10-08
  • 最后修改日期:2025-03-02
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  • 在线发布日期: 2025-11-06
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