金属化球团热态冶金性能对高炉炉料透气性的影响
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作者单位:

1.宝钢股份武钢有限公司 炼铁厂,湖北 武汉 430083 ;2.重庆赛迪热工环保工程技术有限公司,重庆 401122 ;3.武汉科技大学 省部共建耐火材料与冶金国家重点实验室,湖北 武汉 430081

作者简介:

刘志豪(1982—),男,工程师,从事烧结球团的技术研发及固废资源处理工艺研究工作。

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中图分类号:

TF046.6

基金项目:

国家自然科学基金资助项目(51604199)


Effect of high⁃temperature metallurgical properties of metallized pellets on breathability of blast furnace charge
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Affiliation:

1.Wuhan Iron and Steel Co.,Ltd.,Wuhan 430083 ,Hubei,China ;2.Chongqing CISDI Thermal & EnvironmentalEngineering Co.,Ltd.,Chongqing 401122 ,China ;3.The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,Wuhan 430081 ,Hubei,China

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    摘要:

    金属化球团作为新型高炉原料,其强度及热态冶金性能对炉料透气性有重要影响。 本文通过实验室模拟高炉气固还原过程,研究金属化球团冶金特性及物化特征变化对炉料透气性的影响。 结果表明:金属化球团疏松多孔的结构利于还原反应的进行,具有比氧化球团更快的还原反应速率和更高的还原度;金属化球团与氧化球团低温还原粉化性能相近,但具有更低的还原膨胀率、更高的滴落温度和较窄的熔化区间。 在还原过程中,金属化球团中的 MgO 会抑制铁晶须的生成,避免球团发生恶性膨胀;MFe 形成的铁连晶可强化金属化球团的结构,但 Zn 会显著破坏球团结构。 采用金属化球团代替部分氧化球团不会出现高炉炉料强度明显下降、透气性恶化等问题,但金属化球团的高锌含量限制了其在高炉炉料中的配入量。 提高金属化球团的初始强度、降低球团含锌量是改善炉料透气性的方向之一。

    Abstract:

    As a new blast furnace raw material,the strength and high-temperature metallurgical properties of metallized pellets have an important impact on the breathability of furnace charge. In this paper, the influence of metallurgical properties and physicochemical characteristics of metallized pellets on the breathability of furnace charges is studied by simulating the gas-solid reduction process of blast furnace in the laboratory. The results show that the loose and porous structure of metallized pellets is conducive to the reduction reaction,and has a faster reduction reaction rate and higher reduction degree than oxidized pellets. Metallized pellets have similar low-temperature reduction powdering properties to oxidized pellets,but have lower reduction expansion rate, higher soft melt dripping temperature and narrower soft melt range. During the reduction process, MgO in metallized pellets can inhibit the formation of iron whiskers and avoid malignant expansion of the pellets. The iron adhesion formed by MFe could strengthen the structure of metallized pellets, but Zn would significantly damage the pellet structure. The use of metallized pellets instead of partial oxidized pellets will not cause problems such as significant decrease in the strength of blast furnace charges and deterioration of breathability, but the high zinc content of metallized pellets limits their dosage in blast furnace charges. Improving the initial strength of metallized pellets and reducing the zinc content of pellets is one of the directions to improve the breathability of the charge.

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刘志豪,王爱萍,彭浩,程彬,何环宇,周进东.金属化球团热态冶金性能对高炉炉料透气性的影响[J].烧结球团,2025,50(4):48-55

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  • 收稿日期:2024-04-26
  • 最后修改日期:2024-10-29
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  • 在线发布日期: 2025-11-06
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