活性炭原料选择、活化方法及改性技术的研究进展
CSTR:
作者:
作者单位:

1.国家能源集团科学技术研究院有限公司 低碳智能燃煤发电与超净排放全国重点实验室,江苏 南京 210023 ;2.东南大学 a.能源与环境学院 ;b.能源热转换及其过程测控教育部重点实验室,江苏 南京 210096

作者简介:

张乾(1986—),男,高级工程师,从事烟气污染物治理工艺与装备开发的研究工作。

通讯作者:

中图分类号:

TQ424.1;X701.3

基金项目:

低碳智能燃煤发电与超净排放全国重点实验室开放课题资助项目(D2023FK082)


Research progress on selection,activation method and modification technology of activated carbon raw materials
Author:
Affiliation:

1.State Key Laboratory of Low⁃carbon Smart Coal⁃fired Power Generation and Ultra⁃clean Emission,China EnergyScience and Technology Research Institute Co.,Ltd.,Nanjing 210023 ,Jiangsu,China ;2.Southeast University a.Schoolof Energy and Environment ;b.Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education,Nanjing 210096 ,Jiangsu,China

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    活性炭因其优异的吸附性能和经济效益,被视为一种有效的脱硫脱硝材料。 本文从活性炭的原料选择、活化方法和改性技术三个方向,系统地综述改性活性炭用于工业废气中脱除 SO2 和 NOx 的研究进展;详细讨论不同原料制备活性炭的特点,以及活化方式对活性炭性能的影响,探讨采用酸碱改性、金属氧化物负载、氨改性、紫外改性、微波改性、纳米材料复合改性等方式来进一步增强活性炭的功能性。 结果表明:对比煤基、生物质等多种原料,低阶煤、高木质素和富氮生物质是制备高性能活性炭的优选原料。 物理与化学活化方式通过调控孔结构和比表面积,显著影响其吸附性能。 多种改性方法进一步提升了功能性:金属氧化物负载利用氧化还原循环增强催化性能;氨改性引入含氮官能团,提高表面碱性和气体亲和力;矿石负载则实现性能与成本的平衡。 此外,紫外辐照、微波加热及纳米材料复合等新型改性手段有望进一步强化反应位点与结构稳定性,但其在工艺复杂性、成本控制及规模化应用方面仍面临挑战。 总之,活性炭通过结构优化与功能改性展现出高效协同脱硫脱硝的潜力,是实现工业清洁排放的重要材料基础。

    Abstract:

    Activated carbon is regarded as an effective desulfurization and denitrification material due to its excellent adsorption performance and economic benefits. This paper systematically reviews the research progress of modified activated carbon for the removal of SO2 and NOx from industrial waste gas from three directions:raw material selection,activation method and modification technology. The characteristics of activated carbon prepared from different raw materials and the influence of activation methods on the performance of activated carbon are discussed in detail,and the functions of activated carbon are further enhanced by acid-base modification,metal oxide loading,ammonia modification,ultraviolet modification, microwave modification, and nanomaterial composite modification. The results show that compared with coal-based,biomass,and other raw materials,low-rank coal,high lignin and nitrogen-rich biomass are the preferred raw materials for the preparation of high-performance activated carbon. Physical and chemical activation methods significantly affect the adsorption performance by regulating pore structure and specific surface area. A variety of modification methods further improve the functionality:metal oxide loading uses redox cycling to enhance catalytic performance;ammonia modification introduces nitrogen-containing functional groups to improve surface alkalinity and gas affinity; ore loading balances performance and cost. In addition, new modification methods such as ultraviolet irradiation, microwave heating, and nanomaterial composite are expected to further strengthen the reaction site and structural stability, but they still face challenges in process complexity,cost control,and large-scale application. In conclusion,activated carbon demonstrates the potential of efficient and collaborative desulfurization and denitrification through structural optimization and functional modification,and is an important material basis for achieving clean industrial emissions.

    参考文献
    相似文献
    引证文献
引用本文

张乾,张雯澜,庄柯,张博雅,许芸,李晓曼,张亚平,沈凯.活性炭原料选择、活化方法及改性技术的研究进展[J].烧结球团,2025,50(4):14-31

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2024-07-08
  • 最后修改日期:2024-10-25
  • 录用日期:
  • 在线发布日期: 2025-11-06
  • 出版日期:
文章二维码