混装焦丁对高块矿配比含铁炉料软熔行为的影响
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王 广 (1985—),男,博士,副教授,从事低碳炼铁和资源综合利用方面的研究。

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TF532

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国家自然科学基金资助项目 (U1960205)


Effect of mixed nut coke on soft melt performance of iron-bearing charges with high lump ore ratio
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    摘要:

    钢铁工业的低碳化对支撑我国“双碳”目标具有重要意义。提高块矿的入炉比例是降低高炉炼铁碳排放的一个重要措施,而如何减轻高块矿配比高对高炉冶炼过程的不利影响是该工艺应用的关键限制性环节。本文通过软熔试验考察块矿配比、焦丁混装量、焦丁加入方式等对综合炉料软熔行为的影响。结果表明:随着块矿配比由 12% 提升至 24%(块矿完全替代球团矿),软化开始温度和熔化开始温度分别降低 60 ℃和 39 ℃,软化区间较大幅度增加,滴落温度降低,软熔带位置上移。软化区间变宽导致 S 值进一步增大至 195.29 kPa·℃,提高了 30% 以上,即炉料的软熔性能逐渐变差。混装 4 g 焦丁(28.6 kg/t 铁水)条件下熔化开始温度由 1 397 ℃提高至 1 440 ℃,S 值从 185.16 kPa·℃降低至 46.61 kPa·℃,降低了约 75%,料层的透气性明显提高,即显著改善了炉料的软熔性能。但进一步提高混装量则效果不大,此外混装的效果要好于层装。当温度超过熔化开始温度(Ts)时,焦丁的消耗变得明显,其在整个软熔过程中的消耗率为 40% 左右。本文研究结果可为高块矿配比炉料结构下高炉的高效冶炼提供参考。

    Abstract:

    Decarbonization of the steel industry is of great significance to support China’s "dual carbon" goal. Increasing the proportion of lump ore into the furnace is an important measure to reduce the carbon emissions of blast furnace ironmaking, and how to reduce the adverse impact of high lump ore ratio on the blast furnace smelting process is the key limiting link in the application of this process. The effects of lump ore ratio, nut coke mixing amount, and nut coke addition method on the soft melt performance of the comprehensive charge are investigated by a soft melt test. The results show that with the increase of lump ore ratio from 12% to 24% (lump ore completely replaces pellets), the softening onset temperature and melting onset temperature decrease by 60 ℃ and 39 ℃, respectively, the softening interval increases significantly, the dripping temperature decreases, and the position of the soft melt zone increases. The widening of the soft melting interval leads to a further increase in the S value to 195.29 kPa·℃, which is an increase of more than 30%, that is, the soft melt performance of the charge gradually deteriorates. Under the condition of mixed 4 g of nut coke(28.6 kg/t molten iron), the melting start temperature is increased from 1 397 ℃ to 1 440 ℃, and the S value is decreased from 185.16 kPa·℃ to 46.61 kPa·℃, which is reduced by about 75%, and the air permeability of the material layer is significantly improved,that is, the soft melt performance of the charge is significantly improved. However,further increasing the amount of mixing is not very effective, and the effect of outside mixing is better than that of layering. When the temperature exceeds the melting start temperature(Ts), the consumption of nut coke becomes obvious,and its consumption rate is about 40% during the whole soft melting process. The results can provide a reference for the efficient smelting of blast furnace under the structure of high lump ore ratio charge.

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王 广,易青山,韦润培,左海滨,丁 望.混装焦丁对高块矿配比含铁炉料软熔行为的影响[J].烧结球团,2024,(5):24-30

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  • 最后修改日期:2023-11-22
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  • 在线发布日期: 2026-08-27
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