半干法脱硫灰膏体制备流态填筑材料及其机制
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左泽明康 (1998—), 男,硕士研究生,从事固废综合利用及环境工程研究。

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X757

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国家自然科学基金资助项目 (41701624)


Preparation and mechanism of fluid filling materials using semidry desulfurization ash paste system
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    摘要:

    针对填埋到湖底的脱硫灰含水量较高,脱水干燥后再利用可行性差的问题,本文直接利用填埋半干法脱硫灰膏体制备全固废流动态填料。研究“半干法脱硫灰—钢渣微粉—粉煤灰”全固废胶凝材料,考察原料配比对抗压强度的影响,通过 XRD、FT-IR、SEM 等分析手段研究胶凝机理,考察液态填料强度的影响因素。结果表明:原料最佳配比为脱硫灰∶粉煤灰∶钢渣微粉 = 40∶20∶40,28 d 抗压强度可以达到 13.37 MPa;复合胶凝材料水化产物除常规的水化硅酸钙(C—S—H)凝胶和钙矾石外,还存在少量的 Ca3A—CaSO4—11H2O,其由脱硫灰中的 CaSO4·0.5H2O 和体系中的水化铝酸钙(C—A—H)反应生成;当固化剂掺量为 8%~20% 时,所制备的液态填料 28 d 抗压强度为 1.18 ~ 2.47 MPa;三乙醇胺可以增加液态填料各龄期的抗压强度,最佳用量为固化剂质量的 0.04%。

    Abstract:

    In view of the high water content of desulfurized ash buried at the bottom of the lake and the poor feasibility of reuse after dehydration and drying, in this study, the natural properties of semi-dry desulfurized ash paste were directly used to prepare full-solid waste fluid filling material. The "semi-dry desulfurization ash, steel slag powder and fly ash" full-solid waste cementification material was studied. The effect of raw material ratio on compressive strength was investigated. The gelling mechanism was studied by means of XRD, FT-IR, SEM and other analysis methods, and the influencing factors on the strength of fluid filling material were investigated. The results show that, the optimal ratio of raw materials is desulfurization ash: fly ash: steel slag powder = 40: 20: 40, and the compressive strength of 28 d can reach 13.37 MPa. In addition to the conventional C—S—H gel and ettringite, there is also a small amount of hexagonal-shaped crystal C3A—CaSO4—11H2O, which are generated by the reaction of CaSO4·0.5H2O in desulfurization ash and C—A—H in the system. When the ratio of curing agent is in the range of 8%~20%, the 28 d compressive strength of the prepared fluid fill is 1.18 ~ 2.47 MPa. Triethanolamine can improve the compressive strength of the fluid filling at different ages. The best results can be obtained when the dosage is 0.04% of the curing agent mass. When the dosage of curing agent is 8%, the main index of the prepared fluid material meets the standard requirements and the feasibility is good.

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左泽明康,周文波,潘国泰,张瀚文,雷国元.半干法脱硫灰膏体制备流态填筑材料及其机制[J].烧结球团,2024,(4):114-120

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  • 在线发布日期: 2026-08-27
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