低温 SCR 脱硝催化剂失活诊断方法及对策
CSTR:
作者:
作者单位:

作者简介:

梁 磊(1984—),男,高级工程师,从事环境工程专业教学和烟气脱硫、脱硝工程设计及新技术研发方面的工作。

通讯作者:

中图分类号:

X757

基金项目:

江苏省自然科学基金资助项目(BK20181023)


Diagnostic methods and countermeasures for deactivation of low temperature SCR denitration catalyst
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    文章针对石灰回转窑烟气 170 ℃ 低温 SCR 脱硝工程实例,系统连续运行 6 个月,出现脱硝效率下降,催化剂失活现象,为找到失活原因以及解决对策,对催化剂模块进行 BET 比表面积、铵根质量比、SEM-EDS、XRF 检测。SEM 照片显示,催化剂外观没有物理性损伤;催化剂 BET 比表面积下降,表明附着物覆盖了晶体表面孔隙结构;催化剂铵根质量比升高,EDS 和 XRF 检测出催化剂 SO3 质量分数升高,推断催化剂附着物主要成分为硫铵类物质。催化剂热处理后,BET 比表面积升高,证明热处理可以有效去除催化剂表面附着物。此外,文章采用 950 ℃ 左右高温烟气与 170 ℃ 左右的石灰回转窑烟气掺混将烟气升温至 380 ℃,对催化剂进行连续 48 h 热处理。结果表明,热处理能够恢复催化剂脱硝活性,SCR 脱硝系统各项指标恢复至正常运行状态,问题得到有效解决。

    Abstract:

    The article focused on the example of a 170 ℃ low-temperature SCR denitrification project for lime rotary kiln flue gas. The system had been running continuously for 6 months, and there had been a decrease in denitrification efficiency and catalyst deactivation. In order to find the cause of deactivation and solve the problem, BET specific surface area, ammonium radical mass ratio, SEM-EDS, XRF detection were conducted on the catalyst module. SEM photos showed that there was no physical damage to the appearance of the catalyst; The decrease in BET specific surface area of the catalyst indicated that the attachment covers the pore structure of the crystal surface; The ammonium radical mass ratio in the catalyst increased, and EDS and XRF detected an increase in the mass fraction of SO3 content in the catalyst. It was inferred that the main component of the catalyst attachment was ammonium sulfate. After heat treatment of the catalyst, the BET specific surface area was increased, indicating that heat treatment could effectively remove surface attachments on the catalyst. Using high-temperature flue gas at around 950 ℃, mixed with lime rotary kiln flue gas at around 170 ℃, the flue gas was heated to 380 ℃, and the catalyst was subjected to continuous 48 hours of heat treatment. The results were indicated that heat treatment could restore the catalyst denitrification activity, and all indicators of the SCR denitrification system could be restored to normal operating conditions, effectively solving the problem.

    参考文献
    相似文献
    引证文献
引用本文

梁 磊.低温 SCR 脱硝催化剂失活诊断方法及对策[J].烧结球团,2023,48(5):101-107

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2022-08-03
  • 录用日期:
  • 在线发布日期: 2026-10-18
  • 出版日期:
文章二维码