铬渣对烧结矿矿相结构及冶金性能的影响
CSTR:
作者:
作者单位:

作者简介:

徐 菊(1995—),女,硕士研究生,从事冶金资源综合利用方面研究。

通讯作者:

中图分类号:

TF046.4

基金项目:

钢铁冶金新工艺湖北省重点实验室开放基金资助项目(KF-20-3)


Effect of chromium residue on mineralogical structure and metallurgical properties of sinter ore
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    铬渣中含有毒性很强的 Cr(VI) 和大量有价金属铁,将其作为烧结原料不仅可以利用还原性气氛还原铬渣中的 Cr 还可以回收其中的有价金属,实现铬渣的无害化和资源高效利用。为探索在烧结过程中铬渣配比对烧结矿冶金性能的影响,本文开展添加铬渣对烧结矿矿相、烧结参数及烧结矿转鼓强度、低温还原粉化和软熔性能的影响规律研究。研究结果表明:在烧结生产中需控制铬渣配入量为 3% 以下;随着铬渣配比的增加,烧结矿的产量、产率以及烧结速度降低;烧结矿中复合铁酸钙黏结相质量分数减少,硅酸盐黏结相增加,导致烧结矿的转鼓强度由 54.93% 下降到 47.46%;烧结矿中赤铁矿晶粒 由粒状变为斑状以及骸晶状,使低温还原粉化指数由 59.77% 下降到 52.46%,但当铬渣配比增加到 9% 时,矿相中出现了板状赤铁矿和针状复合铁酸钙的交织状结构,低温还原粉化指数增加到 59.07%。由于铬渣中含有 10% 的 Al2O3,生成的富铝渣会降低软化开始温度,增加软化区间,恶化料柱透气性。本文研究成果可为铬渣的综合利用提供理论基础。

    Abstract:

    Chromium residue contains highly toxic Cr(VI) and a large amount of valuable metal iron,which, using it as a sintering raw material, not only can Cr in chromium residue be reduced by using a reducing atmosphere, but also valuable metals can be recovered to realize the harmlessness of chromium residue and efficient use of resources. In order to explore the effect of chromium residue addition on the metallurgical properties of sinter during the sintering process, the influence of chromium residue addition on sinter ore mineragraphy, sintering parameters, sinter tumbler strength, low-temperature reduction pulverization and soft melting performance is studied. The results show that the amount of chromium residue in sintering production needs to be controlled to be less than 3%. With the increase of chromium residue ratio, the output, yield and sintering rate of sinter ore decrease too. The mass fraction of the composite calcium ferrite binder phase decreases and the silicate binder phase increases, resulting in the tumbler strength of the sinter decreasing from 54.93% to 47.46%. The grains of hematite in the sinter ore changes from granular to plaque and skeletal crystalline, which reduces the low-temperature reduction pulverization index from 59.77% to 52.46%, but when the chromium residue ratio increases to 9%, the interwoven structure of tabular hematite and needle-like composite calcium ferrite appears in the ore phase, and the low-temperature reduction pulverization index increases up to 59.07%. Since the chromium residue contains 10% Al2O3, the aluminum-rich residue generated will reduce the softening start temperature, increase the softening interval, and deteriorate the air permeability of the column. The results can provide a certain reference for comprehensive utilization of chromium residue.

    参考文献
    相似文献
    引证文献
引用本文

徐 菊,马国军,郑顶立,张 翔,海远浩.铬渣对烧结矿矿相结构及冶金性能的影响[J].烧结球团,2023,48(4):16-23

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2022-03-25
  • 录用日期:
  • 在线发布日期: 2026-09-29
  • 出版日期:
文章二维码