基于热力学计算的炉料脉石相交互作用研究
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潘玉柱(1989—),男,博士,工程师,从事高炉炼铁、冶金固废资源化利用工作。

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TF521;TF046

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Research on interaction of charge gangue phases based on thermodynamic calculation
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    摘要:

    熔滴试验和单颗粒炉料试验表明,不同性质炉料的脉石相之间存在交互作用,最终形成成分均匀的初渣。本文通过使用 FactSage 热力学计算软件分析不同性质炉料脉石相的熔化及其交互作用机理,阐述不同工艺条件下交互作用对冶炼的影响。研究结果表明,由于矿物组成不同,球团矿相较烧结矿,其脉石相的液相率较高;球团矿和烧结矿脉石相组成的混合初渣,其液相率高于单一烧结矿脉石相的液相率和球团矿、烧结矿脉石相液相率的加权平均值,这说明交互作用可以促进难熔化的烧结矿脉石相熔化;脉石相的液相率随着FeO质量分数的增加而升高。在当前工艺条件下,高碱度烧结矿搭配酸性炉料比使用熔剂型炉料合理。未来氧气高炉和富氢高炉等高还原势高炉可以大量使用酸性炉料和熔剂型炉料。

    Abstract:

    The droplet test and single-particle charge test show that there is interaction between gangue phases of different charges,and an initial slag with uniform composition is formed finally.The melting of gangue phases with different properties and their interaction mechanism are analyzed by using FactSage thermodynamic calculation software,and the influence of interaction on smelting under different technological conditions is expounded.The results show that the liquid phase ratio of gangue phase of pellets is higher than that of sinter due to its different mineral phase composition.The liquid phase ratio of mixed primary slag composed of pellets and sinter gangue phase is higher than that of single sinter gangue phase and the weighted average of liquid phase ratio of pellets and sinter gangue phase,which shows that the interaction can promote the melting of refractory sinter gangue phase;and the liquid fraction of gangue phase increases with the increase of FeO mass fraction.Under current process conditions,high alkalinity sinter with acid charge is more reasonable than flux type charge.In the future,high reducing potential blast furnaces such as oxygen blast furnace and hydrogen-rich blast furnace can use a large number of acid charge and flux charge.

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潘玉柱,丁望,罗大军.基于热力学计算的炉料脉石相交互作用研究[J].烧结球团,2023,48(2):78-84

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  • 最后修改日期:2022-08-07
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  • 在线发布日期: 2026-09-25
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