高炉布袋灰湿法浸出脱氯迁移规律及动力学研究
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苏 航(1994—),男,工程师,从事冶金固废资源化利用技术方面的研究工作。

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TF09;TF803.21

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Research on migration law and dynamics of dechlorination in wet leaching of blast furnace bag dust
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    摘要:

    脱除高炉布袋灰中较高质量分数的氯盐是其资源化利用的一个重要环节。本文以某钢铁企业的高炉布袋灰为研究对象,分析其化学成分,并对湿法浸出前、后布袋灰的微观形貌和晶体组成进行表征,探索湿法脱除机理,进一步研究液固比、浸出时间、搅拌速率、浸出温度等工艺参数对氯离子脱除率的影响。结果表明:高炉布袋灰中的氯主要以氯化锌、氯化钠和氯化钾形式存在;湿法浸出脱氯迁移过程主要是将可溶性氯盐溶解而被脱除的过程,其中液固比对氯盐脱除率的影响最大;在液固比为2,浸出温度为 50 ℃,浸出时间为 10 min,搅拌速率为 200 r/min 的最佳工艺参数条件下,布袋灰中的氯离子可达 90% 以上的脱除率;氯盐脱除主要受扩散条件的影响,其初始反应的表观活化能为 3.24 kJ/mol。

    Abstract:

    It is an important link of resource utilization to remove high mass fraction chlorine salt from blast furnace bag dust. The blast furnace bag dust of an iron and steel enterprise is taken as the research object, its chemical composition is analyzed, and the micro-morphology and crystal composition of the bag dust before and after wet leaching are characterized. The wet removal mechanism is explored, and the effects of process parameters such as liquid-solid ratio, leaching time, stirring rate and leaching temperature on dechlorination rate are further studied. The results show that the chlorine in blast furnace bag dust mainly exists in the form of zinc chloride, sodium chloride and potassium chloride. The migration process of wet leaching dechlorination is mainly the process of dissolving soluble chloride slats and removing it, in which the ratio of liquid to solid has the greatest influence on the dechlorination. Under the optimum conditions of liquid-solid ratio of 2, leaching temperature is 50 ℃, leaching time is 10 min and stirring rate is 200 r/min, the rate of dechlorination in bag dust can reach over 90%. Dechlorination is mainly affected by diffusion conditions, and the apparent activation energy of the initial reaction is 3.24 kJ/mol.

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苏 航,毛 瑞,王 飞,邵久刚.高炉布袋灰湿法浸出脱氯迁移规律及动力学研究[J].烧结球团,2022,47(6):99-105

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  • 最后修改日期:2022-09-20
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  • 在线发布日期: 2026-10-19
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