含碳量对铁基熔体基础物性的影响研究
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王腾飞(1996—),男,硕士研究生,从事熔融还原炼铁方面的研究。

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TF557

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国家自然科学基金资助项目 (52174291)


Influence of carbon content on basic physical properties of iron-based melts
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    摘要:

    在当前碳达峰、碳中和目标的背景下,钢铁行业承担着艰巨的减碳任务,同时也为钢铁行业向绿色环保的低碳冶金方向转型升级提供了机遇。在非高炉炼铁工艺流程中,碳会影响铁水的物性及渣铁界面的反应,而对于正在发展的氢冶金工艺,氢的存在也会对铁中碳的作用行为产生影响。本文从传统高炉冶炼工艺入手,首先对铁水表面张力、渣铁界面张力、铁水黏度及熔化性温度的实验研究方法进行概括,然后分别总结分析了含碳量对铁水表面张力、渣铁界面张力、铁水黏度及熔化性温度的影响。结果表明:含碳量与铁水表面张力没有直接关系,但含碳量会影响氧、硫等表面活性元素在铁水表面的吸附状况,从而影响表面张力;渣铁界面张力与含碳量、温度、炉渣成分,以及渣铁界面处氧的分布情况有关;随着温度的降低,铁水黏度先升高,当温度降低至铁水熔点以下时,黏度又迅速降低,且随着含碳量的升高,转折点温度降低;铁水熔化性温度呈现先降低后升高的趋势。研究结果可为炼铁工作者理解铁基熔体物理性质的影响因素提供参考,对渣铁分离工作提供理论支撑。

    Abstract:

    Under the current background of carbon peaking and carbon neutrality, the iron and steel industry undertakes the arduous task of carbon reduction, and it also provides an opportunity for the iron and steel industry to transform and upgrade towards green and environmentally friendly low-carbon metallurgy. In the non-blast furnace iron-making process, carbon will affect the physical properties of molten iron and the reaction of the slag-iron interface. For the developing hydrogen metallurgy process, the presence of hydrogen will also affect the behavior of carbon in iron. The traditional blast furnace smelting process is started to firstly summarize the experimental research methods of molten iron surface tension, slag-iron interfacial tension, molten iron viscosity and melting temperature, and to summarize and analyze the effect of carbon content on molten iron surface tension, slag-iron interfacial tension, molten iron viscosity and melting temperature. The results show that the carbon content has no direct relationship with the surface tension of molten iron, but the carbon content will affect the adsorption of surface active elements such as oxygen and sulfur on the surface of molten iron, thereby affecting the surface tension; the interfacial tension of slag iron is related to the carbon content, temperature, slag composition, and the distribution of oxygen at the slag iron interface; with the decrease of temperature, the viscosity of molten iron increases first, and when the temperature decreases below the melting point of molten iron, the viscosity decreases rapidly, and with the increase of carbon content, the temperature at the turning point decreases; the molten temperature of molten iron shows a trend of decreasing first and then increasing. The research results can provide references for iron workers to understand the influencing factors of the physical properties of iron-based melts, and provide theoretical support for the separation of slag and iron.

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王腾飞,刘征建,张建良,王耀祖,李洋,王桂林.含碳量对铁基熔体基础物性的影响研究[J].烧结球团,2022,47(1):70-79

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  • 最后修改日期:2022-01-06
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  • 在线发布日期: 2026-10-09
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