磁铁矿氧化球团富氢气基直接还原的特性研究
CSTR:
作者:
作者单位:

作者简介:

潘 建(1977—),男,教授,博士生导师,从事烧结球团及直接还原、二次资源综合利用、复杂难处理矿的综合利用、钢铁冶金环境保护等方面的研究工作。

通讯作者:

中图分类号:

TF046.6

基金项目:

国家自然科学基金资助项目 (52174329)


Study on hydrogen-rich gas-based direct reduction of oxide pellets made by magnetite concentrate
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    以 DRI 为原料的电炉炼钢短流程是冶炼优质钢和特种钢的重要工艺。为制备优质 DRI,本文首先以某全铁品位高达 71.68% 的国产 M 矿为含铁原料制备了 MR=0.09、MR=0.4 球团,然后参考 HYL 法气基直接还原标准,将球团在富氢(H2/CO = 2.6)条件下进行气基直接还原,系统研究了该球团矿的 RI、RSI、还原后 CCS 和物相变化。结果表明:在 800 ~ 950 ℃ 范围内,两种球团矿的 RI 与还原温度线性相关,且 RI 均大于 4;固定还原温度,两种球团矿的 RSI 随着还原的进行先剧增后逐渐下降,在还原度为 50% ~ 80% 之间达到峰值,且 RSI 随还原温度增高而增大;还原过程中,两种球团矿还原后的 CCS 先大幅度下降,后略微上升,且随着还原温度增加而明显降低。整体来看,MR=0.09球团的 RI、RSI 及还原后 CCS 均优于 MR=0.4球团。还原过程由球团外层逐渐向内部推进,在 Fe(H2O(H3转变为 Fe(H3O(H4和浮士体的过程中,球团矿体积膨胀最为严重,导致其内部结构遭到破坏,使球团矿抗压强度大幅度下降,之后金属铁晶粒互连聚集,膨胀率逐渐下降,抗压强度也有所提高。

    Abstract:

    The short process of electric furnace steel-making with DRI as raw material is an important process for smelting high-quality and special steels. In order to prepare high-quality DRI, pellets with MR=0.09 and MR=0.4 are prepared using a domestic M ore with a total iron grade of 71.68% as the iron-bearing raw material. HYL method gas-based direct reduction standard is consulted, the pellets are subjected to gas-based direct reduction under hydrogen-rich (H2/CO = 2.6) conditions, and the RI of the pellets, RSI, CCS and phase change after reduction are systematically studied. The results show that the RI of the two pellets is linearly correlated with the reduction temperature in the range of 800 ~ 950 ℃, and the RI is greater than 4. The RSI of the two pellets increase sharply and then decreased gradually with the reduction, and then reach the peak between 50% and 80%, while the RSI increases with the increase of the reduction temperature. During the reduction process, the CCS of both pellets after reduction first decreases sharply and then increases slightly, and decreases significantly with increasing reduction temperature. Overall, the RI, RSI and reduced CCS of the MR=0.09 pellets are better than those of the MR=0.4 pellets. The reduction process gradually advances from the outer layer of the pellet to the inner layer, and the volume of the pellet expands most severely during the transformation of Fe2O3 to Fe3O4 and faujaite, resulting in the destruction of its internal structure and a significant decrease in the compressive strength of the pellet, followed by the interconnected aggregation of metallic iron grains. The swelling rate gradually decreases and the compressive strength increases.

    参考文献
    相似文献
    引证文献
引用本文

潘建,朱德庆,韩基祥,曹鹏飞,翟勇,陈昭尧,易安南,胡文祥.磁铁矿氧化球团富氢气基直接还原的特性研究[J].烧结球团,2022,47(1):48-57

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2022-01-05
  • 录用日期:
  • 在线发布日期: 2026-10-09
  • 出版日期:
文章二维码