Abstract:In order to explore the performance of low temperature SCR denitration catalyst for sintering flue gas, a low-temperature denitration catalyst is prepared. The SCR denitration test device is constructed in the sintering plant to optimize the research on the relationship between temperature, NH3/NOx molar ratio and denitration efficiency, as well as the continuous operation and regeneration status under the condition of 220 ℃ and 200 ℃. The results show that the denitration efficiency reaches 90.2% ~ 93.6% at 200 ~ 350 ℃, and the NOx meets the ultra-low emission requirement with the increase of temperature. The denitration efficiency increases with the increase of the NH3/NOx molar ratio, the suitable NH3/NOx molar ratio is 1.0. The denitration system operates continuously and keeps stably at 220 ℃, and the catalyst performance is regenerated online at 350 ℃. The regeneration cycle is 6 000 h, and the regeneration time is 150 min. The denitration system has continuously operated for 1 200 h at 200 ℃, the catalyst is seriously blocked, and the regeneration could not restore its performance at 350 ℃. Through the composition analysis, it is inferred that the formation mechanism of the obstruction is that: the inclusions of NH4HSO4 can be easily formed by the original flue gas SOx reacting with the reducing agent NH3, and the inclusions contain charcoal powder and ferric salts that could not be decomposed at 350 ℃. Low temperature denitration catalyst is used in industrial practice, the appropriate temperature should be 220 ℃. To achieve low-temperature denitration at 200 ℃, SOx in the flue gas should be eliminated before denitration.