烧结烟气低温 SCR 脱硝催化剂的制备及试验研究
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梁 磊(1984—),男,高级工程师,硕士生导师,从事环境工程教学及烟气脱硫、脱硝工程设计、新技术研发方面的工作。

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X701

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江苏省自然科学基金资助项目(BK20181023)


Preparation and experimental research on low temperature SCR denitration catalyst for sintering flue gas
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    摘要:

    为探索烧结烟气低温 SCR 脱硝催化剂的使用性能,制备了一种低温脱硝催化剂,在烧结厂区构建 SCR 脱硝试验装置,优化研究温度、NH3/NOx摩尔比与脱硝效率的关系,220℃及 200℃连续运行及再生状况。结果表明:在 200~350℃,脱硝效率达 90.2%~93.6%,且随温度升高而升高,NOx满足超低排放要求;脱硝效率随 NH3/NOx摩尔比增大而增大,适宜 NH3/NOx摩尔比为1.0;220℃脱硝系统连续稳定运行,350℃在线再生恢复催化剂性能,再生周期为 6000 h,再生时长为 150 min;200 ℃脱硝系统连续运行 1200 h,催化剂严重堵塞,350℃再生不能恢复性能。通过成分分析,推断堵塞物形成机理为:原烟气 SOx与还原剂 NH?易形成 NH4HSO4包裹体,包裹体内含有350℃不能分解的炭粉和硫酸铁盐类物质。低温脱硝催化剂应用于工业实践的适宜温度应为220℃,若要实现200℃低温脱硝,应消除脱硝前烟气中的SOx。

    Abstract:

    In order to explore the performance of low temperature SCR denitration catalyst for sintering flue gas, a low-temperature denitration catalyst is prepared. The SCR denitration test device is constructed in the sintering plant to optimize the research on the relationship between temperature, NH3/NOx molar ratio and denitration efficiency, as well as the continuous operation and regeneration status under the condition of 220 ℃ and 200 ℃. The results show that the denitration efficiency reaches 90.2% ~ 93.6% at 200 ~ 350 ℃, and the NOx meets the ultra-low emission requirement with the increase of temperature. The denitration efficiency increases with the increase of the NH3/NOx molar ratio, the suitable NH3/NOx molar ratio is 1.0. The denitration system operates continuously and keeps stably at 220 ℃, and the catalyst performance is regenerated online at 350 ℃. The regeneration cycle is 6 000 h, and the regeneration time is 150 min. The denitration system has continuously operated for 1 200 h at 200 ℃, the catalyst is seriously blocked, and the regeneration could not restore its performance at 350 ℃. Through the composition analysis, it is inferred that the formation mechanism of the obstruction is that: the inclusions of NH4HSO4 can be easily formed by the original flue gas SOx reacting with the reducing agent NH3, and the inclusions contain charcoal powder and ferric salts that could not be decomposed at 350 ℃. Low temperature denitration catalyst is used in industrial practice, the appropriate temperature should be 220 ℃. To achieve low-temperature denitration at 200 ℃, SOx in the flue gas should be eliminated before denitration.

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梁 磊.烧结烟气低温 SCR 脱硝催化剂的制备及试验研究[J].烧结球团,2021,46(3):86-92

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  • 最后修改日期:2020-11-20
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